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Copper Corrosion

Last updated: December 30, 2020

What Does Copper Corrosion Mean?

Copper corrosion is the corrosion of materials made of copper or copper alloys. When exposed to the atmosphere, copper oxidizes, causing normally bright copper surfaces to tarnish. After a few years, this tarnish gradually changes to dark brown or black, and finally to green.

There are two known types of copper corrosion, which are uniform copper corrosion and non-uniform copper corrosion. Copper is also susceptible to crevice corrosion attack.

Copper corrosion occurs at negligible rates in unpolluted air, water and deaerated non-oxidizing acids. However, it is susceptible to more rapid attack in oxidizing acids, oxidizing heavy-metal salts, sulfur, ammonia, and some sulfur and ammonia compounds.

Copper can be toxic and can leach into tap water in both old and new homes. This leaching is a product of corrosion. A small amount of copper consumption is acceptable for humans because it serves as an essential nutrient, but too much may cause gastrointestinal problems. High copper levels over time can lead to liver or kidney damage. If testing of pipes reveals a level greater than 1.0 milligram per liter (mg/l), then treatment is necessary.

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Corrosionpedia Explains Copper Corrosion

Copper is considered to be a noble metal, and as a result is able to resist attack by oxygen. The metal is basically immune to corrosion due to a naturally occurring protective film known as a patina that forms on the metal's surface. If this protective film, usually consisting of reddish-brown cuprous oxide (Cu2O), is destroyed, then copper will eventually corrode. Fortunately, the protective film on copper usually remains intact and repairs itself in most soils.

Types of Copper Corrosion

There are two types of copper corrosion:

  • Uniform corrosion, which is identified by the presence of a relatively uniform layer of copper corrosion byproducts across the inner surface of a pipe wall. It is typically associated with elevated copper levels at the taps.
  • Non-uniform corrosion, which is the isolated development of corrosion cells across the inner surface of a pipe wall. Excessive pitting corrosion can lead to pinhole leaks in the pipe and result in water damage and mold growth.

Conditions That Can Promote Copper Corrosion

Certain conditions can cause corrosion when copper is exposed to particular soils, including:

  • Abnormally aggressive soils
  • Localized and long-line-type concentration cells created by differences in soil composition
  • Action of stray direct currents (DC) flowing in the ground
  • Faulty design and workmanship
  • Certain conditions created by alternating currents (AC)
  • Thermogalvanic effects
  • Galvanic action involving dissimilar materials

Air pollutants (e.g., H2S) change copper’s surface properties, which can considerably lower the adhesion produced by soldering alloys or conductive resins and paste. This change promotes the failure of printed circuit boards in microelectronic devices.

Coupling of copper with aluminum or steel can lead to severe galvanic corrosion. Cyanides are also very corrosive to copper pipes.

The good resistance of copper pipe alloys to corrosion by seawater depends partly upon the inherent cathodic nobility of the metal, but it also depends on copper’s ability to form a protective passive film. High velocity and turbulent flow conditions can remove these films and permit local, rapid corrosion.

Copper corrosion

Figure 1. Copper corrosion of a fastener and surrounding metal. (Source: Twilightartpictures/Dreamstime.com

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Materials SelectionCorrosionCorrosion 101Type of CorrosionElectrochemical PropertyMetalsCorrosion Failure

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